Synthesis and optical properties of phthalocyanine-dihydrobenzocyclobutacenaphthylene systems-Reference-Cited by-同舟云学术

Synthesis and optical properties of phthalocyanine-dihydrobenzocyclobutacenaphthylene systems

Published:2013-09-09 Issue:10 Volume:17 Page:1008-1015
ISSN:1088-4246
Container-title:Journal of Porphyrins and Phthalocyanines
language:en
Short-container-title:J. Porphyrins Phthalocyanines

Author:

Ortiz Javier¹,Parejo Concepción¹,Payá Federico¹,Fernández-Lázaro Fernando¹,Lüer Larry²,Sastre-Santos Ángela¹

Affiliation:

1. División de Química Orgánica, Instituto de Bioingeniería, Universidad Miguel Hernández, 03202 Elche, Spain

2. Madrid Institute for Advanced Studies, IMDEA Nanoscience, C/Faraday 9, Cantoblanco, 28049 Madrid, Spain

Abstract

Four new zinc phthalocyanines (ZnPcs 1–4) peripherally substituted with fully conjugated 6b,10b-dihydrobenzo[j]cyclobut[a]acenaphthylene (DBCA) have been synthesized and chemically characterized. In ( DBCA )4 ZnPc 1 and t Bu 3( DBCA ) ZnPc 2 the DBCA units are directly connected to the phthalocyanine core, meanwhile in ( VDBCA )4 ZnPc 3 and t Bu 3( VDBCA ) ZnPc 4 DCBA units are connected through a vinyl spacer. We describe the effect of the substituents on optical spectra, fluorescence lifetimes and quantum yields.

Publisher

World Scientific Pub Co Pte Lt

Subject

General Chemistry

Link

https://www.worldscientific.com/doi/pdf/10.1142/S1088424613500879

Reference12 articles.

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2. Role of Structural Factors in the Nonlinear Optical Properties of Phthalocyanines and Related Compounds

3. Phthalocyanine-modulated isomerization behaviour of an azo-based photoswitch

4. A Synthesis of Phthaloylnaphthol1

5. .pi.,.pi.-Biradicaloid hydrocarbons. Pleiadene family. I. Photochemical preparation from cyclobutene precursors

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