Synthesis and characterization of a new meso-tetra-dihydro benzocyclobutacenaphthylene free-base porphyrin-Reference-Cited by-同舟云学术

Synthesis and characterization of a new meso-tetra-dihydro benzocyclobutacenaphthylene free-base porphyrin

Published:2018-01 Issue:01n03 Volume:22 Page:173-180
ISSN:1088-4246
Container-title:Journal of Porphyrins and Phthalocyanines
language:en
Short-container-title:J. Porphyrins Phthalocyanines

Author:

İşci Ümit¹,Topal Sevinc Zehra¹,Önal Emel¹,Fidan İsmail¹,Berber Savaş²,Ahsen Vefa¹,Parejo Concepción³,Sastre-Santos Ángela³,Dumoulin Fabienne¹

Affiliation:

1. Gebze Technical University, Department of Chemistry, 41400 Gebze, Kocaeli, Turkey

2. Gebze Technical University, Department of Physics, 41400 Gebze, Kocaeli, Turkey

3. Área de Química Orgánica, Instituto de Bioingeniería, Universidad Miguel Hernández, Avda. de la Universidad, s/n, 03202 Elche, Spain

Abstract

A meso-tetra-6b,10b-dihydrobenzo[j]cyclobut[a]acenaphthylene free-base porphyrin was synthesised and its photophysical, photochemical and electrochemical properties were compared with those of free-base meso-tetraphenylporphyrin. The frontier orbitals and the HOMO–LUMO energy gaps of both compounds were also determined. It was demonstrated that the meso6b,10b-Dihydrobenzo[j]cyclobut[a]acenaphthylene porphyrin retained the same properties as the tetraphenylporphyrin.

Publisher

World Scientific Pub Co Pte Lt

Subject

General Chemistry

Link

https://www.worldscientific.com/doi/pdf/10.1142/S1088424618500062

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2. Modulation of singlet oxygen generation and amphiphilic properties of trihydroxylated monohalogenated porphyrins

3. Flexible synthesis of cationic peptide–porphyrin derivatives for light-triggered drug delivery and photodynamic therapy

4. Photodynamic Action against Wastewater Microorganisms and Chemical Pollutants: An Effective Approach with Low Environmental Impact

5. Trisequential Photooxygenation Reaction: Application to the Synthesis of Carbasugars

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