Crystal structure of a chiral binaphthyl porphyrin

Author:

Rose Eric1,Raoul Nicolas1,Ethève-Quelquejeu Mélanie1,Gallo Emma2,Boitrel Bernard3,Pécaut Jacques4,Dubois Lionel4

Affiliation:

1. Université P. et M. Curie, UPMC Paris 06, IPCM, UMR CNRS 7201, Bâtiment F, Porte 239, Case 181, 4 Place Jussieu, 75252 Paris Cedex 05, France

2. Dipartimento di Chimica Inorganica, Metallorganica e Analitica "Lamberto Malatesta", Università di Milano, and ISTM-CNR, Via Venezian 21, 20133 Milano, Italy

3. Université de Rennes 1 - EENSCR, UMR CNRS 6226, 263 Avenue du General Leclerc, CS 74205, 35042 Rennes Cedex, France

4. Laboratoire de Chimie Inorganique et Biologique, UMR-E 3 CEA -UJF, INAC, CEA-Grenoble, 17 rue des Martyrs, 38054 Grenoble Cedex 9, France

Abstract

Condensation of tetrakis-5,10,15,20-(α,β,α,β-2-aminophenyl)porphyrin atropoisomer with 1,1′-binaphthyl, 2,2′-dimethoxy-3,3′-diacetylchloride afforded the corresponding basket handle porphyrin whose structure has been analyzed by X-ray crystallography. The macrocycle presents a ruffled type plane according to Shelnutt method for classifying and quantifying the out-of-plane and in-plane distortion of a porphyrin. This structure clearly shows the position of the methoxy groups with respect to the center of the porphyrin and their possible role in the enantioselective epoxidation and cyclopropanation of olefins.

Publisher

World Scientific Pub Co Pte Lt

Subject

General Chemistry

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