Highly diastereoselective cyclopropanation of α-methylstyrene catalysed by a C2-symmetrical chiral iron porphyrin complex-Reference-Cited by-同舟云学术

Highly diastereoselective cyclopropanation of α-methylstyrene catalysed by a C2-symmetrical chiral iron porphyrin complex

Published:2014 Issue:15 Volume:50 Page:1811-1813
ISSN:1359-7345
Container-title:Chem. Commun.
language:en
Short-container-title:Chem. Commun.

Author:

Intrieri Daniela¹²³,Le Gac Stéphane⁴⁵⁶⁷,Caselli Alessandro¹²³,Rose Eric⁸⁹¹⁰¹¹¹²,Boitrel Bernard⁴⁵⁶⁷,Gallo Emma¹²³

Affiliation:

1. Dipartimento di Chimica

2. Università degli Studi di Milano

3. 20133 Milano, Italy

4. Institut des Sciences Chimiques de Rennes

5. UMR CNRS 6226

6. Université de Rennes 1

7. 35042 Rennes Cedex, France

8. Université P. et M. Curie

9. UPMC Paris 06

10. IPCM, UMR CNRS 7201

11. Bâtiment F

12. 75252 Paris Cedex 05, France

Abstract

A new chiral iron porphyrin complex performed stereoselective cyclopropanation of α-methylstyrene with outstanding TON and TOF values (up to 20 000 and 120 000 h⁻¹ respectively).

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CC/C3CC48605B

Reference41 articles.

1. Heterocycles from cyclopropanes: applications in natural product synthesis

2. Synthesis of cyclopropane containing natural products

3. Stereoselective Cyclopropanation Reactions

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