In Situ Growth of FeCo-Selenide on Ni Foam as High-Performance Electrode for Electrochemical Energy Storage Devices

Author:

Ye An1,Qi Jiqiu1,Sui Yanwei123ORCID,Yang Fei4,Wei Fuxiang1,He Yezeng1,Meng Qingkun1,Sun Zhi1

Affiliation:

1. School of Materials Science and Engineering, China University of Mining and Technology, Xuzhou 221116, P. R. China

2. The Jiangsu Province Engineering Laboratory of High Efficient Energy Storage Technology and Equipment, Xuzhou 221116, P. R. China

3. The Xuzhou City Key Laboratory of High Efficient Energy Storage Technology and Equipment, Xuzhou 221116, P. R. China

4. School of Engineering Faculty of Science and Engineering, University of Waikato, Private Bag 3105, Hamilton 3240, New Zealand

Abstract

A solid-state energy storage device has been fabricated using FeCo-selenide nanosheet arrays as positive electrode and Fe2O3 nanorod as negative electrode. As an electrode material, the ternary FeCo-selenide nanosheet arrays supported by Ni foam show a highest specific capacitance of 978 F/g (specific capacity of 163[Formula: see text]mAh/g) at 1 A/g and a superior cycle behavior of 81.2% are obtained after 5000 cycles at current density of 4 A/g. The asymmetric supercapacitor achieves the maximum energy density of 34.6[Formula: see text]W[Formula: see text]h/kg at the power density of 759.6[Formula: see text]W/kg. Furthermore, the superior cycling stability with 83% retention of initial capacitance after 5000 cycles further verify the practical applications of FeCo-selenide//Fe2O3 asymmetric supercapacitor. Meanwhile, the LED bulb and the light board of “CUMT” are lighted by connecting several capacitors to form a series circuit.

Funder

Fundamental Research Funds for the Central Universities

Publisher

World Scientific Pub Co Pte Lt

Subject

Condensed Matter Physics,General Materials Science

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