Geographical classification of Nanfeng mandarin by near infrared spectroscopy coupled with chemometrics methods

Author:

Zhang Xuan1,Du Yiping1,Tong Peijin1,Wei Yuanlong2,Wang Man1

Affiliation:

1. Shanghai Key Laboratory of Functional Materials Chemistry and Research Center of Analysis and Test, East China University of Science and Technology, Meilong Rd 130, Shanghai, P. R. China 200237, P. R. China

2. Comprehensive Technology Center of Jiangxi Entry-Exit Inspection and Quarantine Bureau and Jiangxi Province Engineering Research Center of Infrared Spectroscopy Application, South Gan River Avenue 2666, Nanchang, Jiangxi Province, P. R. China 330038, P. R. China

Abstract

Near infrared spectroscopy (NIRS), coupled with principal component analysis and wavelength selection techniques, has been used to develop a robust and reliable reduced-spectrum classification model for determining the geographical origins of Nanfeng mandarins. The application of the changeable size moving window principal component analysis (CSMWPCA) provided a notably improved classification model, with correct classification rates of 92.00%, 100.00%, 90.00%, 100.00%, 100.00%, 100.00% and 100.00% for Fujian, Guangxi, Hunan, Baishe, Baofeng, Qiawan, Sanxi samples, respectively, as well as, a total classification rate of 97.52% in the wavelength range from 1007 to 1296 nm. To test and apply the proposed method, the procedure was applied to the analysis of 59 samples in an independent test set. Good identification results (correct rate of 96.61%) were also received. The improvement achieved by the application of CSMWPCA method was particularly remarkable when taking the low complexities of the final model (290 variables) into account. The results of the study showed the great potential of NIRS as a fast, nondestructive and environmentally acceptable method for the rapid and reliable determination for geographical classification of Nanfeng mandarins.

Publisher

World Scientific Pub Co Pte Lt

Subject

Biomedical Engineering,Atomic and Molecular Physics, and Optics,Medicine (miscellaneous),Electronic, Optical and Magnetic Materials

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