EXCITATION WAVELENGTH DEPENDENCE OF LASER ABLATION MECHANISM OF URETHANE–UREA COPOLYMER FILM STUDIED BY NANOSECOND TIME-RESOLVED INTERFEROMETRY

Author:

TADA TAKUJI1,ASAHI TSUYOSHI1,TSUCHIMORI MASAAKI2,WATANABE OSAMU2,MASUHARA HIROSHI1

Affiliation:

1. Department of Applied Physics, Osaka University, Suita, Osaka 565-0871, Japan

2. Toyota Central Research and Development Laboratories Inc., 41-1, Yokomichi, Nagakute, Aichi 480-1192, Japan

Abstract

Etching dynamics of urethane–urea copolymer film was investigated by utilizing nanosecond time-resolved interferometry and tuning excitation wavelength. From the behavior of fringe pattern deformation at the irradiated areas, it is considered that irradiated polymer film was decomposed more effectively with decrease in excitation wavelength. Excitation wavelength dependence of etching dynamics of urethane–urea copolymer film was not well interpreted in terms of total energy density which was stored within the polymer film due to laser irradiation, while photochemical and photothermal processes can explain mostly the results of shorter wavelength (≤ 475 nm) and longer wavelength (≥ 530 nm) excitations, respectively.

Publisher

World Scientific Pub Co Pte Lt

Subject

Physics and Astronomy (miscellaneous),Atomic and Molecular Physics, and Optics,Electronic, Optical and Magnetic Materials

Cited by 3 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Time-Resolved Spectroscopic and Imaging Studies on Laser Ablation of Molecular Systems: From Mechanistic Study to Bio/Nano Applications;Bulletin of the Chemical Society of Japan;2013-07-15

2. Nanosecond laser preparation of C60 aqueous nanocolloids;Journal of Photochemistry and Photobiology A: Chemistry;2009-09

3. Laser nanochemistry;Pure and Applied Chemistry;2006-01-01

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