Affiliation:
1. Sandia National Laboratories, Albuquerque, NM 87185-1421, USA
Abstract
Low energy electron microscopy (LEEM) is used to investigate the dynamics of Pb overlayer growth on Cu(100). By following changes in surface morphology during Pb deposition, we measure the amount of Cu transported to the surface as the Pb first alloys into the surface during formation of the c(4×4) phase and subsequently dealloys during conversion to the c(2×2) phase. We find that the added coverage of Cu during alloying is consistent with the proposed model for the c(4×4) alloy phase, but the added coverage during dealloying is not consistent with the accepted model for the c(2×2) phase. To account for the discrepancy, we propose that Cu atoms are incorporated in the c(2×2) structure. Island growth and step advancement during the transition from the c(2×2) to [Formula: see text] structure agrees with this model. We also use LEEM to identify the order and temperature of the two-dimensional melting phase transitions for the three Pb/Cu(100) surface structures. Phase transitions for the [Formula: see text] and c(4×4) structures are first-order, but the c(2×2) transition is second-order. We determine that rotational domains of the [Formula: see text] structure coarsen from nanometer- to micron-sized dimensions with relatively mild heating (~ 120°C), whereas coarsening of c(4×4) domain requires considerably higher temperatures (~ 400°C). In studies of three-dimensional island formation, we find that the islands grow asymmetrically with an orientational dependence that is directly correlated with the domain structure of the underlying [Formula: see text] phase.
Publisher
World Scientific Pub Co Pte Lt
Subject
Materials Chemistry,Surfaces, Coatings and Films,Surfaces and Interfaces,Condensed Matter Physics
Cited by
13 articles.
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