Role of the Heteroatoms in the Complex Metal Hydride Reduction of 2-t-Butyl-1,3-dioxan-5-one and 3-Oxoquinolizidine: Comparison of Their Reactivity and Stereochemistry with Those of the Corresponding Carbocyclic Compounds
Author:
Publisher
The Chemical Society of Japan
Subject
General Chemistry
Link
https://www.jstage.jst.go.jp/article/bcsj/72/2/72_2_285/_pdf
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1. Diastereofacial selection in nucleophilic additions to unsymmetrically substituted trigonal carbons
2. An electronic interpretation of the stereochemistry of the reduction of cyclohexanones
3. Electronic effects on the stereochemistry of attack on trigonal atoms in six membered rings
4. Stereochemistry of nucleophilic addition to cyclohexanone. The importance of two-electron stabilizing interactions
5. Origin of π-facial stereoselectivity of hydride reduction of cyclohexanones. A new interpretation based on quantitative analysis of exterior frontier orbital extension
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