Origin of π-facial stereoselectivity of hydride reduction of cyclohexanones. A new interpretation based on quantitative analysis of exterior frontier orbital extension
Author:
Publisher
Elsevier BV
Subject
Organic Chemistry,Drug Discovery,Biochemistry
Reference45 articles.
1. Stereochemistry and mechanism of ketone reductions by hydride reagents
2. Diastereofacial selection in nucleophilic additions to unsymmetrically substituted trigonal carbons
3. Stereochemistry of nucleophilic addition to cyclohexanone. The importance of two-electron stabilizing interactions
4. Reversal of .pi.-facial diastereoselection upon electronegative substitution of the substrate and the reagent
5. Electronic control of .pi.-facial selectivities in nucleophilic additions to 7-norbornanones
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1. Theoretical Study on the Mechanism and Diastereoselectivity of NaBH4 Reduction;The Journal of Physical Chemistry A;2009-02-16
2. The Danishefsky pyranone puzzle: an explanation based on the exterior frontier orbital extension model;Tetrahedron Letters;2009-01
3. Orbital Phase Environments and Stereoselectivities;Orbitals in Chemistry;2009
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5. Solvent effects on the diastereoselection in LiAlH4 reduction of α-substituted ketones;Tetrahedron Letters;2008-06
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