Affiliation:
1. Contribution from the Department of Physical Chemistry, Faculty of Chemistry, University of Seville
Abstract
The equivalence of the Pseudophase and related models, frequently used in the interpretation of kinetic data under restricted geometry conditions, and the well known Brönsted's equation, used in the interpretation of the reactivity in homogeneous media, has been proven in several cases. The generalisation in relation to other non-kinetic properties such as reaction free energy and redox potentials has also been considered.
Subject
Physical and Theoretical Chemistry
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