A New Formulation for Quenching Processes under Restricted Geometry Conditions in the Slow Exchange Limit-Reference-Cited by-同舟云学术

A New Formulation for Quenching Processes under Restricted Geometry Conditions in the Slow Exchange Limit

Published:2014-06 Issue:2 Volume:39 Page:151-170
ISSN:1471-406X
Container-title:Progress in Reaction Kinetics and Mechanism
language:en
Short-container-title:Progress in Reaction Kinetics and Mechanism

Author:

Sanchez F.¹,Barrios A.¹,Lopez-Lopez M.²,Lopez-Cornejo P.¹,Bernal E.¹,Sarrion B.¹,Lebron J.A.¹,Marchena M.¹

Affiliation:

1. The Department of Physical Chemistry, University of Sevilla, C/Profesor Garcia Gonzalez s/n, 41012 Sevilla, Spain

2. Department of Chemical Engineering, Physical Chemistry and Organic Chemistry, University of Huelva, Avenida de las Fuerzas Armadas s/n, Huelva, 21071, Spain

Abstract

A quantitative treatment of quenching processes under restricted geometry conditions in the Slow Exchange Limit is presented. The expressions for KSV have been obtained for this limit in some common situations that can arise in studies under restricted geometry conditions, such as an inhomogeneous quencher distribution in the solution, the presence of oxygen in solution, or the case of solutions containing a mixture of receptors. These situations have been considered and incorporated into the treatment.

Publisher

SAGE Publications

Link

http://journals.sagepub.com/doi/pdf/10.3184/146867814X13981545065017

Reference9 articles.

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2. On the Equivalence of the Pseudophase Related Models and the Brönsted Approach in the Interpretation of Reactivity under Restricted Geometry Conditions

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4. Thermodynamic and structural study of pyrene-1-carboxaldehyde/DNA interactions by molecular spectroscopy: Probing intercalation and binding properties

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