A One-pot Preparation of Isothiocyanates from Amines Using Two Phosgene Substitutes: Bis-(trichloromethyl) Carbonate and Trichloromethyl Chloroformates-Reference-Cited by-同舟云学术

A One-pot Preparation of Isothiocyanates from Amines Using Two Phosgene Substitutes: Bis-(trichloromethyl) Carbonate and Trichloromethyl Chloroformates

Published:2005-09 Issue:9 Volume:2005 Page:585-586
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Bian Gaofeng¹,Shan Weiguang¹,Su Weike¹

Affiliation:

1. College of Pharmaceutical Sciences, Zhejiang University of Technology, Hangzhou, Zhejiang, 310014, P.R. China

Abstract

A series of isothiocyanates have been prepared in high yields in a one-pot reaction from commercial amines and carbon disulfide under mild conditions using bis(trichloromethyl)carbonate (BTC) and trichloromethyl chloroformate (TCF) as reagents in the presence of base.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823405774308862

Reference22 articles.

1. Isothiocyanates in the chemistry of heterocycles

2. The Reactions of Hydroiodide of 2-Amino-1-substituted Guanidine Derivatives with Aromatic Isothiocyanates

3. Synthesis of14C-labelled sulforaphane

4. Synthesis of 1, 1′, 2, 2′, 3, 3′, 4, 4′ - octadeutero-sulforaphane

5. In Vitro Antiproliferative Activity of Isothiocyanates and Nitriles Generated by Myrosinase-Mediated Hydrolysis of Glucosinolates from Seeds of Cruciferous Vegetables

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