Ring a Aromatic Steroids in the Pregnane Series-Reference-Cited by-同舟云学术

Ring a Aromatic Steroids in the Pregnane Series

Published:2006-07 Issue:7 Volume:2006 Page:417-419
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Uyanik Cavit¹,Malay Aslihan²,Hanson James R.³,Hitchcock Peter B.³,Tiryakioglu Serpil³

Affiliation:

1. Department of Chemistry, University of Kocaeli, Izmit 41380, Kocaeli, Turkey

2. Department of Chemistry, Gebze Institute of Technology, P.K. 141, Gebze, 41400, Kocaeli, Turkey

3. Department of Chemistry, University of Sussex, Brighton, Sussex BN1 9QJ, UK

Abstract

4-Methylpregna-1,3,5(10)-trien-20-one and 4-methylpregna-1,3,5(10),16-tetraen-20-one have been obtained by a dienol: benzene type of rearrangement of 5α,6α-epoxypregnanes possessing a further double bond equivalent on ring A. The crystal structure of 4-methyl-19-norpregna-1,3,5(10)-trien-20-one is reported.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823406777980619

Reference9 articles.

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3. for a review see HartshornM.P., and KirkD.N., Steroid Reaction Mechanism, Elsevier, Amsterdam, 1968, p. 283.

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