The Schenck Rearrangement of Allylic Hydroperoxides-Reference-Cited by-同舟云学术

The Schenck Rearrangement of Allylic Hydroperoxides

Published:2009-09 Issue:9 Volume:2009 Page:533-544
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Davies Alwyn G¹

Affiliation:

1. Chemistry Department, University College London, 20 Gordon Street, London WC1H 0AJ, UK

Abstract

It is 50 years since Schenck's discovery of the ubiquitous rearrangement of allylic hydroperoxides, and its unique homolytic mechanism has now been clarified by a combination of experimental and computational methods. The recognised examples of the reaction are surveyed and the way in which the present mechanistic picture has emerged is reviewed. A brief account is given of the closely related Smith epimerisation of allylic hydroperoxides.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823409X12491375725131

Reference54 articles.

1. Neuartige Allyl-Umlagerung von Steroid-Hydroperoxyden. Zur photosensibilisierten Autoxydation der Steroide, II

2. Zur photosensibilisierten Autoxydation der Steroide: Δ5-Steroid-7α-hydroperoxyde und -7-ketone durch Allylumlagerung von Δ6-Steroid-5α-hydroperoxyden

3. Sterol metabolism. XX. Cholesterol 7.beta.-hydroperoxide

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