A Fortuitously Straightforward Synthesis of 4-Acetoxy-2-Propyltetrahydrothiophene-Reference-Cited by-同舟云学术

A Fortuitously Straightforward Synthesis of 4-Acetoxy-2-Propyltetrahydrothiophene

Published:2015-12 Issue:12 Volume:39 Page:724-726
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Ma Bianbian¹,Yang Shaoxiang¹,Tao Feiyan²,Sun Baoguo¹,Liu Yongguo¹,Tian Hongyu¹

Affiliation:

1. Beijing Advanced Innovation Center for Food Nutrition and Human Health, Beijing Key Laboratory of Flavour Chemistry, Beijing Technology and Business University, Beijing 100048, P.R. China

2. Technical Research & Development Center, Chuanyu Branch of China Tobacco Corporation, Chengdu, P.R. China

Abstract

4-Acetoxy-2-propyltetrahydrothiophene was synthesised from 1-hepten-4-ol by a three-step route involving epoxidation and mesylation to 1,2-epoxy-4-heptyl mesylate and then reaction with thioacetate. An acetoxylated cyclic product was formed instead of the expected thioacetate, and a mechanism for its formation using an intramolecular transesterification is proposed.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/174751915X14476078040135

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Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Syntheses of 4-Acetoxy- or Acetylthio-2-substituted Tetrahydrothiophene;HETEROCYCLES;2018

2. ChemInform Abstract: A Fortuitously Straightforward Synthesis of 4-Acetoxy-2-propyltetrahydrothiophene.;ChemInform;2016-04