Three-Component Reaction between Trivalent Phosphorus Nucleophiles, Dialkyl Acetylenedicarboxylates and (2,4-Dinitrophenyl) Acetic Acid-Reference-Cited by-同舟云学术

Three-Component Reaction between Trivalent Phosphorus Nucleophiles, Dialkyl Acetylenedicarboxylates and (2,4-Dinitrophenyl) Acetic Acid

Published:2012-08 Issue:8 Volume:36 Page:497-499
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Hassanabadi Alireza¹,Mosslemin Mohammad H.²,Abyar Elaheh²,Taleb-Malamiri Mohammad²

Affiliation:

1. Department of Chemistry, Islamic Azad University, Zahedan Branch, PO Box 98135-978, Zahedan, Iran

2. Department of Chemistry, Islamic Azad University, Yazd Branch, PO Box 89195-155, Yazd, Iran

Abstract

A three-component reaction between dialkyl acetylenedicarboxylates (DAADs) and phosphites in the presence of (2,4-dinitrophenyl)acetic acid leads to dialkyl 2-(dialkoxyphosphoryl)-3-[3-acetyl-2-(2,4-dinitrophenyl)-4-oxosucci-nates in excellent yields. A similar reaction with triphenylphosphine, instead of phosphites, produces the stabilised phosphoranes in good yields.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/174751912X13403013285904

Reference16 articles.

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4. Preparation of Scalemic P-Chiral Phosphines and Their Derivatives

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