Utilization of cage germoxanes as templates for tuning pore characteristics of siloxane-based materials-Reference-Cited by-同舟云学术

Utilization of cage germoxanes as templates for tuning pore characteristics of siloxane-based materials

Published:2024-02-05 Issue:3 Volume:53 Page:
ISSN:0366-7022
Container-title:Chemistry Letters
language:en
Short-container-title:

Author:

Hayashi Taiki¹^ORCID,Matsuno Takamichi¹²³^ORCID,Kuroda Kazuyuki¹²^ORCID,Shimojima Atsushi¹²³^ORCID

Affiliation:

1. Department of Applied Chemistry, Faculty of Science and Engineering, Waseda University , 3-4-1 Okubo , Shinjuku-ku, Tokyo 169-8555, Japan

2. Kagami Memorial Research Institute for Materials Science and Technology, Waseda University , 2-8-26 Nishiwaseda , Shinjuku-ku, Tokyo 169-0051, Japan

3. Waseda Research Institute for Science and Engineering, Waseda University , 3-4-1 Okubo , Shinjuku-ku, Tokyo 169-8555, Japan

Abstract

Abstract We demonstrate the utilization of cage germoxanes as templates for tuning the pore characteristics of siloxane-based materials. Molecular-scale composites of cage germoxanes and cage siloxanes were prepared by hydrosilylation reactions between SiH- and vinyl-modified cage siloxanes in the presence of vinyl-modified cage germoxanes. Subsequent acid treatments selectively removed the germoxane moiety, resulting in variation in the pore structures. These results contribute to developing a novel method for tuning the pore characteristics of siloxane-based nanoporous materials.

Funder

JSPS KAKENHI

JST SPRING

JSPS Research Fellowships for Young Scientists

Publisher

Oxford University Press (OUP)

Link

https://academic.oup.com/chemlett/advance-article-pdf/doi/10.1093/chemle/upae025/56586502/upae025.pdf

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