Direct cross-linking of silyl-functionalized cage siloxanes <i>via</i> nonhydrolytic siloxane bond formation for preparing nanoporous materials-Reference-Cited by-同舟云学术

Direct cross-linking of silyl-functionalized cage siloxanes via nonhydrolytic siloxane bond formation for preparing nanoporous materials

Published:2024 Issue:14 Volume:53 Page:6256-6263
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kikuchi Miharu¹,Hayashi Taiki¹^ORCID,Matsuno Takamichi¹²³^ORCID,Kuroda Kazuyuki¹²^ORCID,Shimojima Atsushi¹²³^ORCID

Affiliation:

1. Department of Applied Chemistry, Faculty of Science and Engineering, Waseda University, 3-4-1 Okubo, Shinjuku-ku, Tokyo 169-8555, Japan

2. Kagami Memorial Research Institute for Materials Science and Technology, Waseda University, 2-8-26 Nishiwaseda, Shinjuku-ku, Tokyo 169-0051, Japan

3. Waseda Research Institute for Science and Engineering, Waseda University, 3-4-1 Okubo, Shinjuku-ku, Tokyo 169-8555, Japan

Abstract

Nonhydrolytic siloxane bond formation reactions between cage siloxanes modified with dimethylsilyl and dimethylethoxysilyl groups in the presence of B(C6F5)3 catalyst are conducted to produce nanoporous materials with well-defined 3D networks.

Funder

New Energy and Industrial Technology Development Organization

Japan Science and Technology Corporation

Ministry of Education, Culture, Sports, Science and Technology

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00215F

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