Effects of simulated secondary organic aerosol water on PM1 levels and composition over the US
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Published:2023-10-30
Issue:21
Volume:23
Page:13555-13564
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ISSN:1680-7324
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Container-title:Atmospheric Chemistry and Physics
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language:en
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Short-container-title:Atmos. Chem. Phys.
Author:
Kakavas Stylianos, Pandis Spyros N., Nenes AthanasiosORCID
Abstract
Abstract. Water is a key component of atmospheric aerosol, affecting many aerosol processes including gas-to-particle partitioning of semi-volatile compounds. Water related to secondary organic aerosol (SOAW) is often neglected in atmospheric chemical transport models and is not considered in gas-to-particle partitioning calculations for inorganic species. We use a new inorganic aerosol thermodynamics model, ISORROPIA-lite, which considers the effects of SOAW, to perform chemical transport model simulations for 1 year over the continental United States to quantify its effects on aerosol mass concentration and composition. SOAW can increase average fine aerosol water levels by up to a factor of 2 when secondary organic aerosol (SOA) is a major PM1 component. This is often the case in the south-eastern US, where SOA concentrations are higher. Although the annual average impact of this added water on total dry PM1 concentrations due to increased partitioning of nitrate and ammonium is small (up to 0.1 µg m−3), total dry PM1 increases of up to 2 µg m−3 (with nitrate levels increases of up to 200 %) can occur when RH levels and PM1 concentrations are high.
Funder
Horizon 2020 H2020 European Research Council
Publisher
Copernicus GmbH
Subject
Atmospheric Science
Reference56 articles.
1. Baker, A., Kanakidou, M., Nenes, A., Myriokefalitakis, S., Croot, P.L., Duce, A. D., Gao, Y., Guieu, C., Ito, A., Jickells, T. D., Mahowald, N. M., Middag, R., Perron, M. M. G., Sarin, M. M., Shelley, R., and Turner, D. R.: Changing atmospheric acidity as a modulator of nutrient deposition and ocean biogeochemistry, Sci. Adv., 7, 1–9, https://doi.org/10.1126/sciadv.abd8800, 2021. 2. Bian, Y. X., Zhao, C. S., Ma, N., Chen, J., and Xu, W. Y.: A study of aerosol liquid water content based on hygroscopicity measurements at high relative humidity in the North China Plain, Atmos. Chem. Phys., 14, 6417–6426, https://doi.org/10.5194/acp-14-6417-2014, 2014. 3. Bougiatioti, A., Nikolaou, P., Stavroulas, I., Kouvarakis, G., Weber, R., Nenes, A., Kanakidou, M., and Mihalopoulos, N.: Particle water and pH in the eastern Mediterranean: source variability and implications for nutrient availability, Atmos. Chem. Phys., 16, 4579–4591, https://doi.org/10.5194/acp-16-4579-2016, 2016. 4. Carlton, A. G. and Turpin, B. J.: Particle partitioning potential of organic compounds is highest in the Eastern US and driven by anthropogenic water, Atmos. Chem. Phys., 13, 10203–10214, https://doi.org/10.5194/acp-13-10203-2013, 2013. 5. Chang, R. Y.-W., Slowik, J. G., Shantz, N. C., Vlasenko, A., Liggio, J., Sjostedt, S. J., Leaitch, W. R., and Abbatt, J. P. D.: The hygroscopicity parameter (κ) of ambient organic aerosol at a field site subject to biogenic and anthropogenic influences: relationship to degree of aerosol oxidation, Atmos. Chem. Phys., 10, 5047–5064, https://doi.org/10.5194/acp-10-5047-2010, 2010.
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