Development of an incoherent broadband cavity-enhanced absorption spectrometer for measurements of ambient glyoxal and NO<sub>2</sub> in a polluted urban environment
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Published:2019-04-24
Issue:4
Volume:12
Page:2499-2512
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ISSN:1867-8548
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Container-title:Atmospheric Measurement Techniques
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language:en
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Short-container-title:Atmos. Meas. Tech.
Author:
Liang Shuaixi, Qin Min, Xie Pinhua, Duan Jun, Fang Wu, He Yabai, Xu Jin, Liu JingweiORCID, Li XinORCID, Tang Ke, Meng Fanhao, Ye Kaidi, Liu JianguoORCID, Liu Wenqing
Abstract
Abstract. We report the development of an instrument for
simultaneous fast measurements of glyoxal (CHOCHO) and NO2 based on
incoherent broadband cavity-enhanced absorption spectroscopy (IBBCEAS) in
the 438–465 nm wavelength region. The highly reflective cavity mirrors
were protected from contamination by N2 purge gas. The reduction of the
effective cavity length was calibrated by measuring collision-induced oxygen
absorption at ∼477 nm of pure oxygen gas input with and
without the N2 mirror purge gas. The detection limits of the developed
system were evaluated to be 23 parts per trillion by volume (pptv, 2σ) for CHOCHO and 29 pptv (2σ) for NO2 with a 30 s acquisition
time. A potential cross-interference of NO2 absorption on
accurate CHOCHO measurements has been investigated in this study, as the
absorption of NO2 in the atmosphere could often be several hundred-fold
higher than that of glyoxal, especially in contaminated areas. Due to
non-linear spectrometer dispersion, simulation spectra of NO2 based on
traditional convolution simulation did not match the measurement spectra
well enough. In this work, we applied actual NO2 spectral profile
measured by the same spectrometer as a reference spectral profile in
subsequent atmospheric spectral analysis and retrieval of NO2 and
CHOCHO concentrations. This effectively reduced the spectral fitting
residuals. The instrument was successfully deployed for 24 d of
continuous measurements of CHOCHO and NO2 in the atmosphere in a
comprehensive field campaign in Beijing in June 2017.
Publisher
Copernicus GmbH
Subject
Atmospheric Science
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