Ni-MnO2 Synthesized by One-Step Liquid Phase Coprecipitation as Promising Electrode Materials for Supercapacitor

Author:

Zhou Yue1,Yang Qing Hao1,Dong Jie1

Affiliation:

1. Xi'an University of Science and Technology

Abstract

Nickel-doped manganese dioxide (Ni-MnO2) as electrode materials for supercapacitors were successfully prepared by one-step chemical liquid phase coprecipitation with the different nickel doped proportions. X-ray diffraction (XRD), scanning electron microscopy (SEM) and X-ray fluorescence (XRF) were used to analyze the micro-structure, morphology and composition. And electrochemical properties were studied by cyclic voltammetry (CV), galvanostatic charge-discharge (GCD) and electrochemical impedance spectrometry (EIS). The results revealed that MnO2 synthesized in this work turned out to be δ-MnO2 of homogeneous dispersion and excellent electrochemical properties. Specific capacitance of 300.85 F/g was achieved for the 2% Ni-doped MnO2 at 2mV/s through cyclic voltammetry, and after 5000 circles the persistence rate of which still remained to 75%, exhibiting a preeminent advantage of stability and reversibility to naked MnO2.

Publisher

Trans Tech Publications, Ltd.

Subject

Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science

Reference21 articles.

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