Selective High-Throughput TiN Etching Methods

Author:

Cooper Emanuel I.1,Rajaram Rekha2,Payne Makonnen2,Lippy Steven1

Affiliation:

1. Advanced Technology Materials Incorporation

2. Intermolecular Incorporation

Abstract

Titanium nitride (TiN) is widely used as a hard mask film protecting the inter-level dielectric (ILD) before metal or plating seed layer deposition steps. It is common practice to use a wet etch in order to remove residues formed during the ILD dry-etch step, and at the same time to remove some or all of the exposed TiN. From its thermochemical properties, it might be predicted that wet etching of TiN should be easy, since it is quite unstable with respect to both plain and oxidative hydrolysis. For example, in acidic solutions at 25°C [1, :

Publisher

Trans Tech Publications, Ltd.

Subject

Condensed Matter Physics,General Materials Science,Atomic and Molecular Physics, and Optics

Reference5 articles.

1. Lange's Handbook of Chemistry, 13th ed. (McGraw-Hill, 1985).

2. J.B. Lee: Corrosion 37 (1981), p.467.

3. S. O'Brien, D.A. Prinslow and J.T. Manos, US 6200910.

4. Yongxun Liu & al., Jpn. J. Appl. Phys. 49 (2010), p. 06GH18/1.

5. E. Cooper & al., US 8026200.

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