Modeling and Simulation of the Sulfur Dioxide Adsorption Process in Natural Zeolites

Author:

Sfechiş Susana1,Abrudean Mihail2,Sas Diana Monica2,Ungureşan Mihaela Ligia2,Clitan Iulia2,Mureşan Vlad2

Affiliation:

1. University of Agricultural Sciences and Veterinary Medicine Cluj-Napoca

2. Technical University of Cluj-Napoca

Abstract

The paper presents a solution for modeling and simulation of the adsorption process of the sulfur dioxide in natural zeolites. The adsorption process is modeled as a distributed parameter process, its dynamics depending on three independent variables: time and two spatial variables. In order to simulate the adsorption process, an original form of the approximating analytical solution which describes the process work in dynamical regime is proposed and used. The coefficients of the approximating analytical solution are determined using experimental data obtained from the real plant. A direct practical application, resulted through the simulation of the obtained mathematical model, is the approximation of the time period in which the saturation of the zeolites of different dimensions occurs. Having the mentioned time period, the operators from the industrial field can decide with precision the moment when a zeolite block has to be replaced in order to avoid the environment pollution.

Publisher

Trans Tech Publications, Ltd.

Reference7 articles.

1. D. Axente, A. Bâldea, M. Abrudean, I. Roman and V. Bidian: SO2 and CO2 adsorption in natural zeolites from Romania. Chemistry Journal. Vol. 31, No. 7 (1980), p.656.

2. M. -L. Ungureşan, V. Mureşan, M. Abrudean, I. Clitan and T Coloşi: Modeling and Simulation of the Gas Absorption Process in the Liquid Phase. ICMERA 2014, Applied Mechanics and Materials Vol. 656 (2014), p.81.

3. R. Dugas, G. Rochelle, Absorption and desorption rates of carbon dioxide with monoethanolamine and piperazine, Energy Procedia, Vol. 1 (1), (2009), p.1163–1169.

4. D. Axente, M. Abrudean and A. Bâldea: Adsorption on Romanian natural clinoptilolite. Zeolites. Vol. 3 (1983), p.259.

5. H. -X. Li and C. Qi: Spatio-Temporal Modeling of Nonlinear Distributed Parameter Systems: A Time/Space Separation Based Approach, 1st Edition, edited by Springer Publishing House, 2011, pg. 194.

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