Synthesis and Characterization of Al4SiC4: A “New” Wide Band Gap Semiconductor Material

Author:

Zevgitis Dimitrios1,Chaix-Pluchery Odette1,Doisneau Beatrice1,Modreanu Mircea2,La Manna Joseph1,Sarigiannidou Eirini1,Chaussende Didier1

Affiliation:

1. University Grenoble Alpes

2. University College Cork

Abstract

High temperature solution growth of Al4SiC4 single crystals was carried out from the melt of silicon and aluminium pieces in a graphite crucible used as carbon source (typically 1800°C under 1 bar of argon). The obtained crystals, in the mm scale, were then characterized by a variety of techniques including: Raman spectroscopy, transmission electron microscopy techniques, X-ray diffraction and UV-Vis-NIR spectroscopy. A good structural quality was revealed by TEM, ensuring a well resolved Raman spectrum. The UV-Vis transmission spectrum shows an optical gap located around 2-2.5 eV.

Publisher

Trans Tech Publications, Ltd.

Subject

Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science

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