Abstract
Amorphous fine powder in the Li2O-Al2O3-TiO2-P2O5 (LATP) system were prepared directly from a
mixture of Li2O, Al2O3, TiO2, and P2O5 as starting materials using a mechanical milling technique at
room temperature. LATP glass-ceramics were obtained by heat treatment of the mechanochemically
prepared amorphous powder over the crystallization temperature. X-ray diffraction peaks due to
LiTi2(PO4)3 and AlPO4 crystals for LATP glass-ceramics were observed. Thus, high lithium ion
conducting LATP glass-ceramics solid electrolytes were prepared successfully from the
mechanochemically prepared amorphous powder. The LATP glass-ceramic fine particles were
investigated as coating materials of LiCoO2 cathode in lithium ion batteries. The LATP
glass-ceramics coated LiCoO2 electrode materials exhibited a good charge-discharge performance for
charging up to a high voltage (4.5 V vs. Li/Li+).
Publisher
Trans Tech Publications, Ltd.
Subject
Mechanical Engineering,Mechanics of Materials,General Materials Science
Cited by
5 articles.
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