Corrosion Behaviors of Borosilicate Glasses in Various Leaching Agents

Author:

Wu Ping Ping1,Zhang Cheng1,Xu Hai Fang2,Huang De Xin2,Xu Bing2,Jiang Dan Yu2

Affiliation:

1. Shanghai Institute of Technology

2. Chinese Academy of Science

Abstract

Static short-term corrosion tests were performed to two kinds of borosilicate glasses in deionized water, at 70°C and 150°C, respectively. Same corrosion experiments were also carried out in other leaching agents, such as simulated under ground water of Beishan, sulfuric acid solution (pH=0.5) and potassium hydroxide solution (pH = 13). Experimental results show that both leaching agent and corrosion temperature co-dominate the corrosion process, and the temperature plays more important role. At low temperature of 70°C, the corrosion reaction is controlled by the ion diffusing in DIW at earlier stage. While in PHS, network hydrolysis reaction is the main corrosion mechanism.

Publisher

Trans Tech Publications, Ltd.

Subject

General Engineering

Reference10 articles.

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3. G.Q. Xu, J. Wang, H.L. Zheng, et al.: Geological Disposal of Radioactive Waste in the World (Atomic Energy Press, Beijing, China, 1999), p.48.

4. L.L. Hench, D.E. Clark, A.B. Harker, et al: J. Mater. Sci. Vol. 21(1986), p.1457.

5. W.L. Ebert: Phy. Chem. Glasses. Vol. 34.

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