Hexagonality and Stacking Sequence Dependence of Etching Properties in Cl2-O2-SiC System

Author:

Hatayama Tomoaki1,Koketsu Hidenori1,Yano Hiroshi1,Fuyuki Takashi1

Affiliation:

1. Nara Institute of Science and Technology

Abstract

Thermal etching of hexagonal (4H-, 6H-, 8H- and 10H-), rhombohedral (15R- and 21R-), and cubic (3C-) SiC Si-faces was performed between 900 and 1000oC in a mixed gas of chlorine (Cl2) and oxygen (O2). In the case of well oriented Si-faces, the 3C-SiC (111) substrate was etched fastest in polytypes. The etching rate in the dislocation-free area depended on the hexagonality. Etch pits with definite shapes appeared, which depend on the type of dislocation and crystal structures. On the basis of these results, etching properties are discussed.

Publisher

Trans Tech Publications, Ltd.

Subject

Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science

Reference7 articles.

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2. R.W. Bartlett and M. Barlow: J. Electrochem. Soc. Vol. 117 (1970), p.1436.

3. R.C. Marshall and J.W. Faust, Jr.: Silicon Carbide 1973 (University of South Carolina Press, Columbia, SC, 1973) p.215 and p.659.

4. J. Takahashi, M. Kanaya and Y. Fujiwara: J. Cryst. Growth Vol. 135 (1994) p.61.

5. T. Hatayama, T. Shimizu, H. Kouketsu, H. Yano, Y. Uraoka and T. Fuyuki: Jpn. J. Appl. Phys. Vol. 48 (2009) pp.066516-1.

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