A Novel Method for Evaluation of Chromium Evaporation from Solid Oxide Fuel Cells Interconnects: A Feasibility Study-Reference-Cited by-同舟云学术

A Novel Method for Evaluation of Chromium Evaporation from Solid Oxide Fuel Cells Interconnects: A Feasibility Study

Published:2021-01-05 Issue: Volume:1016 Page:1109-1113
ISSN:1662-9752
Container-title:Materials Science Forum
language:
Short-container-title:MSF

Author:

Paravidino Daniele¹,Piccardo Paolo¹,Spotorno Roberto¹^ORCID

Affiliation:

1. Università degli Studi di Genova

Abstract

The evaporation of volatile chromium species from ferritic stainless steels (FSSs) used as interconnect is well-known as degradation source for planar solid oxide fuel cell (SOFC) stacks. This work presents a feasibility study to quantify chromium evaporation from FSSs. It is based on measuring carbon dioxide produced by an intermediate reaction. Cr evaporated is collected by sodium carbonate forming sodium chromate and carbon dioxide. Measuring the resulting carbon dioxide allowed to quantify online the amount of reacted chromium with the carbonates. The post-experiment quantification of sodium chromate confirmed the applicability of the proposed method.

Publisher

Trans Tech Publications, Ltd.

Subject

Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science

Link

https://www.scientific.net/MSF.1016.1109.pdf

Reference12 articles.

1. A.B. Stambuli, E. Traversa, Solid oxide fuel cells: a review of an environmental clean and efficient source of energy, Renew. Sustain Energy Rev. 6 (2002) 433-455.

2. J. Ryter, R. Amendola, M. McCleary, W.-J. Shong, C.-K. Liu, R. Spotorno, P. Piccardo, Effect of electrical current on the oxidation behavior of electroless nickel-plated ferritic stainless steel in solid oxide fuel cell operating conditions, International Journal of Hydrogen Energy 43 (2018) 426-434.

3. Z. B. Stoynov, D. E. Vladikova, B. G. Burdin, J. Laurencin, D. Montinaro, A. Nakajo, P. Piccardo, A. Thorel, M. Hubert, R. Spotorno, A. Chesnaud, Differential Resistance Analysis - A New Tool for Evaluation of Solid Oxide Fuel Cells Degradation, MRS Advances 2 (2017) 3991-4003.

4. P. Piccardo, A. Pecunia, V. Bongiorno, R. Spotorno, Z. Wuillemin, J. P. Ouweltjes, Aging of Materials at Inlet and Outlet Fuel Manifolds in a SOFC Stack, ECS Transactions 68 (2015) 2611-2624.

5. E.J. Opila, D.L. Myers, N.S. Jacobson, I.M.B. Nielsen, D.F. Jonson, J.K. Olminsky, Theorical and experimental investigation of the thermochemistry of CrO2(OH)2((g). J Phys Chem A 111 (2007) 1971-1980.

Cited by 5 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Effect of Pressure on High-Temperature Oxidation of Ferritic Stainless Steels;Materials Science Forum;2023-11-29

2. Investigation of a Metallic Interconnect Extracted from an SOFC Stack after 40,000 h of Operation;Energies;2022-05-12

3. Test and Modelling of Solid Oxide Fuel Cell Durability: A Focus on Interconnect Role on Global Degradation;Energies;2022-04-09

4. Volatilization of chromium from AISI 441 stainless steel: Time and temperature dependence;Surface and Coatings Technology;2022-03

5. On the High-Temperature Oxidation and Area Specific Resistance of New Commercial Ferritic Stainless Steels;Metals;2021-03-01