Author:
Kadentsev V.I.,Chizhov A.O.,Chizhov O.S.,Kolotyrkina N.G.,Kutin A.A.,Nesterov I.D.,Chuvylkin N.D.,Rzheznikov V.M.,Golubovskaya L.E.
Abstract
Collision-induced fragmentation of the [M + Na]+ and [M + H]+ ions generated from 3-[4- bis-N,N-(2-chloroethyl)aminophenyl]-acetates in the estrane series under electrospray/ionization was studied. Some regularities in fragmentation pathways depending on the nature of functional groups were established. Formation of the [(M + Na) – NaCl]+ ions along with [(M + Na) – HCl]+ ions from the [M + Na]+ ions was explained using quantum chemical calculations for some simplified models.
Subject
Spectroscopy,Atomic and Molecular Physics, and Optics,General Medicine
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