The intent of this current exploration is to examine the natural convective magnetohydrodynamics (MHD) mass transfer flow past an infinite vertical porous plate implanted in a porous medium with thermal diffusion and chemical reaction. An analytical solution for momentum, energy, and concentration equations is achieved by implementing the perturbation method. A uniform magnetic field is installed orthogonally with the plate and the fluid undergoes a normal suction velocity with the consideration that heat flux at the plate is constant. In contemplation of recording the influence of different nondimensional parameters and deliberating the flow characteristics, the computational aftermath for fluid velocity, temperature, and species concentration is portrayed graphically. Investigations divulge the fact that the increase in thermal diffusivity causes hefty falls in the temperature field and improves the concentration of the fluid. Again it is also noted that the fluid velocity and species concentration dwindle as a result of a high rate of consumption of species. The solutions obtained in this study are attained asymptotically.