Abstract
In this study, the molecular interactions occurring during Chemical Mechanical planarization of Copper in Ferric nitrate–Alumina–Benzotriazole system is investigated. This system is characterized by sudden and dramatic transitions in removal rates when experimental parameters such as downforce and concentrations of the slurry components (Benzotriazole, abrasive, oxidizer) are varied. This behavior is interpreted in terms of the three surface kinetic processes viz. Cu dissolution, film formation and film removal by abrasion, that determine the overall removal rate. A phenomenological model incorporating Frumkin isotherm for the adsorption of Benzotriazole molecules and Langmuir isotherm for the adsorption of surfactants/ions is proposed. Mathematical equations relating the rates of film formation, film removal and metal dissolution to the overall removal rates are derived. The model is validated by comparing the model predictions with experimental data. The non-linear equations describing the sudden transitions are shown to exhibit a cusp catastrophe when the interaction parameter exceeds a certain value.
Publisher
The Electrochemical Society