Anodizing Aluminum and Its Alloys in Etidronic Acid to Enhance Their Corrosion Resistance in a Sodium Chloride Solution

Author:

Kikuchi TatsuyaORCID,Suzuki Yusuke,Iwai Mana,Suzuki Ryosuke O.ORCID

Abstract

The formation behaviors of the anodic oxide film that forms on various commercially available aluminum plates were investigated by galvanostatic anodizing in etidronic acid, and their corrosion resistances were examined in a 3.5 wt% NaCl solution. High-purity aluminum and A1050, A5052, and A7075 aluminum alloys were galvanostatically anodized in an etidronic acid solution. An amorphous porous oxide film formed on the pure aluminum, the A1050 alloy, and the A5052 alloy, whereas a plasma electrolytic oxidation (PEO) film formed on the A7075 alloy. The nanopores formed in the porous oxide film could be sealed with hydroxides by immersion in boiling water. Corrosion-resistant pure aluminum with a measured corrosion current density of i corr = 10−9 Am−2 could be formed by anodizing and subsequent pore-sealing. Although the corrosion current increased due to the presence of alloying elements in the matrix, the fabrication of the corrosion-resistant A1050 and A5052 alloys with i corr = 10−6 Am−2 could also be achieved by anodizing. Alternately, the corrosion resistance of the A7075 alloy covered with the PEO film was measured to be i corr = 10−4 Am−2, which is not as small as the i corr of the A1050 and A5052 alloys due to its open microporous structure.

Funder

the Fundamental Research Developing Association for Shipbuilding and Offshore

the Salt Science Research Foundation

Ministry of Education, Culture, Sports, Science and Technology

Japan Society for the Promotion of Science

the Light Metal Educational Foundation

Publisher

The Electrochemical Society

Subject

Materials Chemistry,Electrochemistry,Surfaces, Coatings and Films,Condensed Matter Physics,Renewable Energy, Sustainability and the Environment,Electronic, Optical and Magnetic Materials

Cited by 6 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3