Abstract
Lead-carbon hybrid ultracapacitors (Pb-C HUC) are the solution to the sulfation issue of lead-acid batteries. The Pb-C HUCs are of much interest due to the aqueous system with longer cycle life and higher power density. Here, honeycomb structured porous activated carbons with 1790 m2 g−1 of surface area were synthesized from Carica papaya biowaste by chemical treatment followed by carbonization at 800 °C (PAC-800). PAC-800 composite electrode delivers a specific capacitance of 250 F g−1 at 1 Ag−1 and has 10000 stable cycle life in 4.5 M H2SO4. Further, a kinetic study of the PAC-800 electrode illustrates that at 2 mV s−1, they show 61% of capacitive and 39% of pseudocapacitive charge storage. Pb-C HUCs fabricated using in situ activated PbO2 sheet as cathode and PAC-800 composite electrode as anode delivers 390 F g−1 at 1 A g−1 and have 93% capacitance retention over 15000 cycles at 5 A g−1. Further, the current Pb-C HUC results are compared with commercially available high surface area (2484 m2 g−1) carbons based Pb-C HUCs. This work illustrates an easy, scalable synthesis root for biowaste carbons and their electrochemical performance in Pb-C HUCs, which is on par with commercial high surface area carbons.
Publisher
The Electrochemical Society
Subject
Materials Chemistry,Electrochemistry,Surfaces, Coatings and Films,Condensed Matter Physics,Renewable Energy, Sustainability and the Environment,Electronic, Optical and Magnetic Materials
Cited by
2 articles.
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