Characterization of Jarosite Formed upon Bacterial Oxidation of Ferrous Sulfate in a Packed-Bed Reactor

Author:

Grishin Sergei I.1,Bigham Jerry M.1,Tuovinen Olli H.1

Affiliation:

1. Departments of Microbiology and Agronomy, 2 The Ohio State University, Columbus, Ohio 43210

Abstract

A packed-bed bioreactor with activated-carbon particles as a carrier matrix material inoculated with Thiobacillus ferrooxidans was operated at a pH of 1.35 to 1.5 to convert ferrous sulfate to ferric sulfate. Despite the low operating pH, trace amounts of precipitates were produced in both the reactor and the oxidized effluent. X-ray diffraction and chemical analyses indicated that the precipitates were well-ordered potassium jarosite. The chemical analyses also revealed a relative deficiency of Fe and an excess of S in the reactor sample compared with the theoretical composition of potassium jarosite.

Publisher

American Society for Microbiology

Subject

Ecology,Applied Microbiology and Biotechnology,Food Science,Biotechnology

Reference16 articles.

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2. Sulfate studies IV: the jarosite-natrojarosite-hydronium jarosite solid solution series;Brophy G. P.;Am. Mineral.,1965

3. A chemical study of some synthetic potassium-hydronium jarosites;Brown J. B.;Can. Mineral.,1970

4. Jarosite-goethite stabilities at 25°C, 1 atm;Brown J. B.;Mineral. Depos.,1971

5. Dutrizac J. E. 1984. The behavior of impurities during jarosite precipitation p. 125-169. In R. G. Bautista (ed.) Hydrometallurgical process fundamentals. Plenum Publishing Corp. New York.

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