Dissociation dynamics of a diatomic molecule in an optical cavity-Reference-Cited by-同舟云学术

Dissociation dynamics of a diatomic molecule in an optical cavity

Published:2022-12-28 Issue:24 Volume:157 Page:244109
ISSN:0021-9606
Container-title:The Journal of Chemical Physics
language:en
Short-container-title:J. Chem. Phys.

Author:

Mondal Subhadip¹^ORCID,Wang Derek S.²^ORCID,Keshavamurthy Srihari¹^ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Technology, Kanpur, Uttar Pradesh 208 016, India

2. Harvard John A. Paulson School of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts 02138, USA

Abstract

We study the dissociation dynamics of a diatomic molecule, modeled as a Morse oscillator, coupled to an optical cavity. A marked suppression of the dissociation probability, both classical and quantum, is observed for cavity frequencies significantly below the fundamental transition frequency of the molecule. We show that the suppression in the probability is due to the nonlinearity of the dipole function. The effect can be rationalized entirely in terms of the structures in the classical phase space of the model system.

Publisher

AIP Publishing

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

https://aip.scitation.org/doi/pdf/10.1063/5.0124085

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