Affiliation:
1. Laboratoire de Chimie et Physique Quantiques LCPQ/FERMI, UMR5626, Université de Toulouse (UPS) and CNRS , 118 Route de Narbonne, F-31062 Toulouse, France
Abstract
Although clusters made of polycyclic aromatic hydrocarbon and water monomers are relevant objects in both atmospheric and astrophysical science, little is known about their energetic and structural properties. In this work, we perform global explorations of the potential energy landscapes of neutral clusters made of two pyrene units and one to ten water molecules using a density-functional-based tight-binding (DFTB) potential followed by local optimizations at the density-functional theory level. We discuss the binding energies with respect to various dissociation channels. It shows that cohesion energies of the water clusters interacting with a pyrene dimer are larger than those of the pure water clusters, reaching for the largest clusters an asymptotic limit similar to that of pure water clusters and that, although the hexamer and octamer can be considered magic numbers for isolated water clusters, it is not the case anymore when they are interacting with a pyrene dimer. Ionization potentials are also computed by making use of the configuration interaction extension of DFTB, and we show that in cations, the charge is mostly carried by the pyrene molecules.
Funder
HORIZON EUROPE European Research Council
Agence Nationale de la Recherche
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Cited by
5 articles.
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