Noncritical interface near a critical end point

Author:

Widom B.

Publisher

AIP Publishing

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference33 articles.

1. Free Energy of a Nonuniform System. I. Interfacial Free Energy

2. Critical Points in Multicomponent Systems

3. Thermodynamic model for tricritical points in ternary and quaternary fluid mixtures

4. In this same limiting case φ = 0, but with the alternative identifications ofQas −ψβ and ψβγ as ψγ, we have χ = −(ψγ−ψβ)∕(ψβ−ψα), and then Eq. (6c) becomes, instead, the formula for σα−γ, the tension of the α−γ interface, which is the sum of the α−γ and β−γ interfacial tensions.

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