Revealing microheterogeneities and second order phase transitions in aqueous mixtures of 1-propoxypropan-2-ol at 298 K-Reference-Cited by-同舟云学术

Revealing microheterogeneities and second order phase transitions in aqueous mixtures of 1-propoxypropan-2-ol at 298 K

Published:2016 Issue:26 Volume:18 Page:17506-17516
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Lampreia Isabel M. S.¹²³⁴⁵,Santos Ângela F. S.¹²³⁴⁵,Borges Carlos M.⁶²³⁴⁵,Santos M. Soledade C. S.⁶²³⁴⁵,Moita Maria-Luísa C. J.⁶²³⁴⁵,Reis João Carlos R.¹²³⁴⁵

Affiliation:

1. Centro de Química Estrutural

2. Faculdade de Ciências

3. Universidade de Lisboa

4. 1749-016 Lisboa

5. Portugal

6. Centro de Química e Bioquímica

Abstract

Second-order phase transitions, identified by Kirkwood–Buff integrals, assigned to solution microheterogeneities are corroborated by ESI-MS, surface tension and solvatochromic parameters.

Funder

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP02408D

Reference71 articles.

1. Model systems for hydrophobic interactions: Volumes and heat capacities ofn-alkoxyethanols in water

2. Thermodynamics of aqueous mixtures of nonelectrolytes. I. Excess volumes of water-n-alcohol mixtures at several temperatures

3. Thermodynamic and related studies of amphiphile + water systems