Two-center three-electron bonding in ClNH3 revealed via helium droplet infrared laser Stark spectroscopy: Entrance channel complex along the Cl + NH3 → ClNH2 + H reaction-Reference-Cited by-同舟云学术

Two-center three-electron bonding in ClNH3 revealed via helium droplet infrared laser Stark spectroscopy: Entrance channel complex along the Cl + NH3 → ClNH2 + H reaction

Published:2016-04-22 Issue:16 Volume:144 Page:164301
ISSN:0021-9606
Container-title:The Journal of Chemical Physics
language:en
Short-container-title:J. Chem. Phys.

Author:

Moradi Christopher P.¹,Xie Changjian²,Kaufmann Matin³,Guo Hua²,Douberly Gary E.¹

Affiliation:

1. Department of Chemistry, University of Georgia, Athens, Georgia 30602-2556, USA

2. Department of Chemistry and Chemical Biology, University of New Mexico, Albuquerque, New Mexico 87131, USA

3. Department of Physical Chemistry II, Ruhr-University Bochum, D-44801 Bochum, Germany

Funder

U.S. Department of Energy (DOE)

Publisher

AIP Publishing

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://aip.scitation.org/doi/am-pdf/10.1063/1.4947089

Reference59 articles.

1. THE NATURE OF THE CHEMICAL BOND. II. THE ONE-ELECTRON BOND AND THE THREE-ELECTRON BOND

2. Three-electron bond

3. Structures and stabilities of singly charged three-electron hemibonded systems and their hydrogen-bonded isomers

4. A Theoretical Study of Chlorine Atom and Methyl Radical Addition to Nitrogen Bases: Why Do Cl Atoms Form Two-Center−Three-Electron Bonds Whereas CH3 Radicals Form Two-Center−Two-Electron Bonds?

5. What can we learn from two-center three-electron bonding with the topological analysis of ELF?

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