A Theoretical Study of Chlorine Atom and Methyl Radical Addition to Nitrogen Bases: Why Do Cl Atoms Form Two-Center−Three-Electron Bonds Whereas CH3 Radicals Form Two-Center−Two-Electron Bonds?
Author:
Affiliation:
1. Contribution from the Department of Chemistry, Auburn University, Auburn, Alabama 36849, and Research School of Chemistry, Australian National University, Canberra, ACT 0200, Australia
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja9613973
Reference57 articles.
1. σ*-Radicals R3N — hal: electron paramagnetic resonance studies of the radiolysis of alkylammonium halides
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3. Pyridine complexes of chlorine atoms
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