Quantum state-dependent anion–neutral detachment processes

Abstract

The detachment loss dynamics between rubidium atoms (Rb) and oxygen anions (O−) are studied in a hybrid atom–ion trap. The amount of excited rubidium present in the atomic ensemble is actively controlled, providing a tool to tune the electronic quantum state of the system and, thus, the anion–neutral interaction dynamics. For a ground state Rb interacting with O−, the detachment induced loss rate is consistent with zero, while the excited state Rb yields a significantly higher loss rate. The results are interpreted via ab initio potential energy curves and compared to the previously studied Rb–OH− system, where an associative electronic detachment reactive loss process hinders the sympathetic cooling of the anion. This implies that with the loss channels closed for ground-state Rb and O− anion, this system provides a platform to observe sympathetic cooling of an anion with an ultracold heavy buffer gas.