From vinylsilanes to organic/inorganic hybrid materials-Reference-Cited by-同舟云学术

From vinylsilanes to organic/inorganic hybrid materials

Published:2005-01-01 Issue:12 Volume:77 Page:2083-2090
ISSN:1365-3075
Container-title:Pure and Applied Chemistry
language:
Short-container-title:

Author:

Luh Tien-Yau¹

Affiliation:

1. 1Department of Chemistry and Institute of Polymer Science and Engineering, National Taiwan University, Taipei 106, Taiwan

Abstract

Alternating regioregular silylene-spaced divinylarene copolymers [(donor-SiMe2-)n=1-3-(acceptor-SiMe2)] are synthesized by rhodium-catalyzed hydrosilylation of bis-alkynes with bisvinylic silyl hydrides. Efficient intrachain energy transfer has been observed in these copolymers. The intensities of emission profiles depend on the relative ratio of donor-to-acceptor chromophores. The corresponding inorganic/organic hybrid materials are synthesized, and their photophysical properties are described.

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

Link

https://www.degruyter.com/document/doi/10.1351/pac200577122083/pdf

Reference5 articles.

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5. for their valuable contributions to this work Thanks are also due to the National Council and the Ministry of Education of the Republic of China for support REFERENCES and and For reviews see Pure;Ni;Science Org Chem Am Chem Soc Synth Chem Res Appl Chem,1988

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