Divergent reactivity of divinylsilanes toward sulfonamides in different oxidative systems
Author:
Affiliation:
1. A. E. Favorsky Irkutsk Institute of Chemistry
2. Siberian Division of Russian Academy of Sciences
3. 664033 Irkutsk
4. Russia
Abstract
The products of NBS-induced halosulfonamidation of divinylsilanes undergo base-induced cyclization providing new heterocycles including the hitherto unknown 1,3,5-diazasilinanes in up to quantitative yield.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/RA/D0RA07469A
Reference17 articles.
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2. Synthesis of Vinylsilanes
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4. Allylsilanes and Vinylsilanes from Silylcupration of Carbon−Carbon Multiple Bonds: Scope and Synthetic Applications
5. Vinylsilane- and alkynylsilane-terminated cyclization reactions
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