Affiliation:
1. 1Institut für Chemie Organische Chemie, Freie Universität Berlin, Takustr. 3, D-14195 Berlin, Germany
Abstract
n-Butyllithium smoothly deprotonates alkoxyallenes at C-1. The generated lithiated species reacts with a variety of electrophiles furnishing after cyclization functionalized furan, pyrrole, or 1,2-oxazine derivatives. The formation of new CC bonds often occurs with high stereoselectivities, which are exploited for efficient and selective syntheses of natural products or other compounds of interest.
Subject
General Chemical Engineering,General Chemistry
Cited by
64 articles.
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