Author:
Rani Deepika,Singh Gursharan,Sharma Seema
Abstract
Reactions of MoCl5/MoO2Cl2 with 4-phenylimidazole-2-thiol/2-thiazoline-2-thiol in CH3CNsolvent in 1:1/1:2 molar ratios have been carried out at room temperature. Products obtained MoCl3(C9H7N2S)(CH3CN), [1];MoCl2(C9H7N2S)(CH3CN), [2]; Mo2OCl4(C9H8N2S)2, [3] and Mo4O2Cl12(C9H7N2S)4, [4]; MoO2Cl3(C3H5NS2)2, [5] and Mo2O4Cl3(C3H5NS2)2, [6] have been analyzed and characterizedby elemental analysis, FTIR, 1H NMR and LC-MS techniques. Compounds being moisture and air sensitive, these have been prepared in inert atmosphere using vacuum line and liquid nitrogen cooled traps. Fragments obtained in LC-MS spectra support the formulae derived.
Publisher
Oriental Scientific Publishing Company
Subject
Drug Discovery,Environmental Chemistry,Biochemistry,General Chemistry
Cited by
5 articles.
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1. Reactions of MoCl5 with 4-Methylpyridine, 2-Methylpyridine and 1-Methylimidazole in Tetrahydrofuran;Oriental Journal Of Chemistry;2021-10-30
2. Reactions of MoCl5 and MoO2Cl2 with Succinimide, 1, 4-Diaminobutane, 3-Methylpyridine, 1, 3-Diaminopropane, Pyrazole and 1- Methylpyrrolidine in Tetrahydrofuran;Oriental Journal Of Chemistry;2021-06-30
3. Reactions of MoCl5 and MoO2Cl2 with Succinimide, 1, 4-Diaminobutane, 3-Methylpyridine, 1, 3-Diaminopropane, Pyrazole and 1- Methylpyrrolidine in Tetrahydrofuran;Oriental Journal Of Chemistry;2021-06-30
4. Reactions of MoOCl4 and MoO2Cl2 with Heterocyclic Thioamides;Oriental Journal Of Chemistry;2021-04-30
5. Reactions of MoO2Cl2 and MoOCl4 with 2-Mercaptopyridine, 4-Phenylimidazole-2-thiol and 6-Mercaptopurine Monohydrate;Oriental Journal Of Chemistry;2021-02-28