Affiliation:
1. Punjab Technical University, Kapurthala India.
2. Department of Applied Chemistry, Giani Zail Singh Campus College of Engineering & Technology,Dabwali Road, MRSPTU Bathinda-151001-India.
Abstract
MoOCl4/MoO2Cl2 were reacted with 2-mercaptopyridine (IUPAC: pyridine-2-thiol)/4-phenylimidazole-2-thiol (IUPAC: 4-phenyl-1, 3-dihydroimidazole-2-thione)/6-mercaptopurine (IUPAC: 1, 7-dihydro-purine-6-thione) in acetonitrile medium using equal/twice molar concentrations at normal temperature. The reactions yielded products: MoOCl3(C5H4NS-SNH4C5).2HCl, [1]; Mo3O3Cl12(C5H4NS-SNH4C5)(CH3CN)2, [2]; Mo2OCl6(C9H7N2S)4, [3] and Mo2O2Cl8(C5H4N4S)(CH3CN), [4]. The various techniques used for characterization of compounds are: Fourier transform infrared, proton nuclear magnetic resonance, 13C nuclear magnetic resonance, liquid/gas chromatography mass spectrometry and C, H, N, S, Mo, Cl analysis. The products are prone to oxidation/hydrolysis by air/moisture, so all procedures were executed in vacuum line using dry nitrogen atmosphere. Elemental analysis and fragments recorded in mass spectrometry are in tune with the formulae proposed.
Publisher
Oriental Scientific Publishing Company
Subject
Drug Discovery,Environmental Chemistry,Biochemistry,General Chemistry
Reference111 articles.
1. https://medlineplus.gov/druginfo/meds/a682653.html.
2. https://en.wikipedia.org/wiki/Mercaptopurine#:~:text=Mercaptopurine%20(6%2DMP)%2C,Crohn’s%20disease%2C%20and%20ulcerative%20colitis.
3. Łakomska, I.; Pazderski, L.; Sitkowsk, J.; Kozerski, L.; Pełczynska, M.; Nasulewicz, A.; Opolski, A.; Szłyk, E., J. Mol. Struct., 2004, 707, 241-247.
4. CrossRef
5. Blank, C.; Dabrowiak, J., J. Inorg. Biochem.,1984, 21, 21-29.
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