Study of kerosene caustic wash process for jet fuel production

Abstract

AbstractCaustic wash is one of many industrial processes that are used to produce jet fuel. In this study, an analysis of the key parameters of the kerosene caustic wash process was conducted to improve the total performance of the treatment process. The investigated parameters are caustic concentration (from 0.03 to 3.0 wt%), caustic volume (from 110% of theoretical to 250%), number of treatment stages (one and two stages), wash water type (demineralized water and alkaline soft water), and wash water volume (10% and 30% of kerosene feed volume). Results revealed that the reaction between sodium hydroxide and naphthenic acids is a diffusion-controlled chemical reaction. The diluted caustic solutions (0.5 wt%) are better than the concentrated ones (3 wt%). Higher excess caustic volume has a slight effect on kerosene acidity. Performing the caustic treatment process in one stage is sufficient, and the two-stage process has no effect on acidity. Washing caustic-treated kerosene with demineralized water (pH=7) has a slight adverse effect on kerosene acidity. Increasing the demineralized water volume results in a slight increase in the acidity of the treated kerosene. Wash water should be slightly alkaline (pH 7.5–8) to prevent the reverse reaction of sodium naphthenates back into naphthenic acid. Increasing wash water volume (more than 10 vol% of kerosene feed) has no noticeable effect on the water content of treated kerosene.