Author:
Ren Jie,Liao Ruirui,Yang Wu,Li Yan,Gao Jinzhang
Abstract
Abstract
Background
A highly absorptive resin poly(butyl acrylate-co-styrene) was synthesized by the method of emulsion polymerization and initiated using glow discharge electrolysis plasma. The effects of the synthesis conditions were examined and discussed in detail. The synthesized resin was characterized by attenuated total reflectance Fourier transform infrared spectroscopy, scanning electron microscopy, and thermogravimetric analysis.
Results
The results showed that the optimal conditions were as follows: discharge voltage 580 V, discharge time 11 min, polymerization temperature 90°C, ratio of water/monomer 4.0, and 3% of N,N-methylenebis(acrylamide).
Conclusion
Under the optimal conditions, the oil absorbency was 97 g/g for chloroform and 56 g/g for xylene. In addition, the kinetics of absorption for oil was investigated, and the results indicated that the absorption process seems to obey more the first-order rate model.
Publisher
Springer Science and Business Media LLC
Subject
Materials Chemistry,General Chemical Engineering,General Chemistry
Reference18 articles.
1. Ji N-Y, Chen H, Yu M-M, Qu R-J, Wang C-H: Synthesis of high oil-absorption resins of poly(methyl methacrylate-butyl methacrylate) by suspended emulsion polymerization. Polym Adv Technol 2011, 22: 1898–1904. 10.1002/pat.1689
2. Farag R-K, El-Saeed S-M: Synthesis and characterization of oil sorbers based on docosanyl acrylate and methacrylates copolymers. J Appl Polym Sci 2008, 109: 3704–3713. 10.1002/app.28594
3. Shan G-R, Xu P-Y, Weng Z-X, Huang Z-M: Synthesis and properties of oil absorption resins filled with polybutadiene. J Appl Polym Sci 2003, 89: 3309–3314. 10.1002/app.12515
4. Guo S-W, Jiang T-K, Lin X, Wu J-Y: Synthesis and properties of nano-oil-absorption resin by emulsion polymerization. J Wuhan Inst Tech 2010, 32: 77–80.
5. Lu J, Shan G-R, Huang Z-M, Weng Z-X: Study on kinetics of styrene/butyl acrylate/crosslinker emulsion copolymerization. Chem React Eng &Tech 2006, 22: 109–113.
Cited by
5 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献