Preparation of Chiral Triacylglycerols, sn-POO and sn-OOP, via Lipase-mediated Acidolysis Reaction

Author:

Yamamoto Yukihiro1,Yoshida Hiroki2,Nagai Toshiharu3,Hara Setsuko2

Affiliation:

1. Faculty of Life and Environmental Sciences, Prefectural University of Hiroshima

2. Faculty of Science and Technology, Seikei University

3. Tsukishima Foods Industry Co., Ltd.

Publisher

Japan Oil Chemists' Society

Subject

General Chemical Engineering,General Medicine,General Chemistry

Reference23 articles.

1. 1) Chakra, W.; Claudio, C.; Peter, W.; Peter, F.; Benjamin, F.; Neeranat, T.; Patrick, P. Docosahexaenoic acid is more stable to oxidation when located at the sn-2 position of triacylglycerol compared to sn-1 (3). J. Am. Oil Chem. Soc. 85, 543-548 (2008).

2. 2) Yamamoto, Y.; Imori, Y.; Hara, S. Oxidation behavior of triacylglycerol containing conjugated linolenic acids in sn-1 (3) or sn-2 position. J. Oleo Sci. 63, 31-37 (2014).

3. 3) Dote, S.; Yamamoto, Y.; Hara, S. Effects of triacylglycerol molecular species on the oxidation behavior of oils containing α-linolenic acid. J. Oleo Sci. 65, 193-199 (2016).

4. 4) R. Jhon, C.; Robert. W.L. Crystallization, polymorphism, and binary phase behavior of model enantiopure and racemic triacylglycerols. Cryst. Growth Des. 11, 1723-1732 (2011).

5. 5) Mizobe. H.; Tanaka, T.; Hatakeyama, N.; Nagai, T.; Ichioka, K.; Hondoh, H.; Ueno, S.; Sato, K. Structures and binary mixing characteristics of enantiomers of 1-oleoyl-2,3-dipalmitoyl-sn-glycerol (S-OPP) and 1,2-dipalmitoyl-3-oleoyl-sn-glycerol (R-PPO). J. Am. Oil Chem. Soc. 90, 1809-1817 (2013).

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